Phenacyl bromide → Phenacyl thiocyanate

HRID 1660671노트

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HRID 1660671 반응식
Br[CH2:2][C:3]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)=[O:4].[SiH4].[S-:12][C:13]#[N:14].[Na+]>C(O)C>[S:12]([CH2:2][C:3]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)=[O:4])[C:13]#[N:14]

참가 물질

5

반응물 3

HCID 6259Phenacyl bromideHCID 23953SilaneHCID 516871Sodium thiocyanate

생성물 1

HCID 219693Phenacyl thiocyanate

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

Bromoacetophenone-modified aminopropylsilylated glass surfaces (2.5×7.5 cm; Sigma, Silane-Prep™, S4651) (see Example 13) were coated with a 0.1M solution of sodium thiocyanate in ethanol and incubated for five hours at 50° C. The glass surfaces thus treated were then washed five times using respectively 30 mL of ethanol for 3 minutes each at room temperature. After washing three times for three minutes each using respectively 30 mL of DCM at room temperature, the glass surfaces were dried and stored at 4° C. until further use.

후처리

  1. additionThe glass surfaces thus treated
  2. washwere then washed five times
  3. customfor 3 minutes
  4. customat room temperature
  5. washAfter washing three times for three minutes each using respectively 30 mL of DCM at room temperature
  6. customthe glass surfaces were dried
  7. customstored at 4° C. until further use

출처 및 근거

ORD 기록
ord-6c69b8cd2f5d46608e9d805dbc1a368d
출처 데이터셋
uspto-grants-2011_10
특허 번호
US08029979B2

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