Triphenylphosphine → Tetradec-7-ene

HRID 1678946

반응식

HRID 1678946 반응식
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].[CH3:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH:23]=[CH:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH3:32].C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.C([Sn](CCCC)(CCCC)CCCC)CCC>[W](Cl)(Cl)(Cl)(Cl)(Cl)Cl>[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].[CH3:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH:23]=[CH:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH3:32].[CH3:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH:21]=[CH:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30]

참가 물질

8

반응물 4

HCID 11776TriphenylphosphineHCID 15098TetrabutyltinHCID 25209Tetradec-7-ene2회HCID 521661CID 5216612회

생성물 3

HCID 25209Tetradec-7-eneHCID 520743Hexadec-7-eneHCID 521661CID 521661

시약·촉매·용매 1

HCID 83301Tungsten hexachloride촉매

실험 절차

7-Tetradecene and 9-octadecene were cross-metathesized employing a homogeneous modified catalyst. For the reaction, 1 mole 7-tetradecene and 1 mole 9-octadecene were combined in the reactor with 13 millimoles tungsten hexachloride. Triphenylphosphine (6.5 millimoles) was then charged to the reactor followed by the addition of 13 millimoles tetrabutyl tin. The reaction was conducted at 115° C and after 330 minutes reaction, near equilibrium conversion of the olefins was obtained with high selectivity to the equilibrium mixture of 1-part 7-tetradecene, 1 part 9-octadecene and 2 parts 7-hexadecene. When the experiment was repeated in an identical manner but using an unmodified catalyst (13 millimoles tungsten hexachloride with 13 millimoles tetrabutyl tin) conversion of the olefins was significantly greater than the theoretical equilibrium conversion due to the lower selectivity of the reaction to the desired cross-metathesized products.

후처리

  1. customreaction

출처 및 근거

ORD 기록
ord-fd439f1193024e988016522ffcf11a14
출처 데이터셋
uspto-grants-1978_03
특허 번호
US04078012

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