Cyclogeraniolane → tert-Butyl peroxybenzoate

HRID 1680667

반응식

HRID 1680667 반응식
C(OO[C:7]1(OOC(C)(C)C)[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1)(C)(C)C.CC1(C)CC(C)CCC1.[C:28]([O:32][O:33][C:34]([O:38]OC(C)(C)C)(CC)C)([CH3:31])([CH3:30])[CH3:29].[C:44]([O:48][O:49][C:50]([O:56]OC(C)(C)C)(CCCC)[CH3:51])([CH3:47])([CH3:46])[CH3:45]>>[CH:12]1[C:7]([C:34]([O:33][O:32][C:28]([CH3:31])([CH3:30])[CH3:29])=[O:38])=[CH:8][CH:9]=[CH:10][CH:11]=1.[C:50]([O:49][O:48][C:44]([CH3:47])([CH3:46])[CH3:45])(=[O:56])[CH3:51]

참가 물질

6

반응물 4

HCID 18309CyclogeraniolaneHCID 763591,1-Bis(tert-butylperoxy)cyclohexaneHCID 2212602,2-Bis(tert-butylperoxy)butaneHCID 23455465HCID 23455465, 화합물

생성물 2

HCID 11966tert-Butyl peroxybenzoateHCID 61019tert-Butyl peroxyacetate

실험 절차

Similar beneficial improvements in the conversion of monomer and physical properties of the polymer are obtained when the 1,1-bis(t-butyl peroxy)cyclohexane is replaced with 1,1-bis(t-butyl peroxy), 3,3,5-trimethylcyclohexane, 2,2-bis(t-butyl peroxy)butane and 2,2-bis(t-butyl peroxy)hexane. Slightly inferior results are obtained when t-butyl perbenzoate and t-butyl peracetate are employed.

후처리

  1. customSlightly inferior results

출처 및 근거

ORD 기록
ord-afe3b2044ecb4d9fa76e5cec4307c148
출처 데이터셋
uspto-grants-1981_06
특허 번호
US04275182

연결된 노트

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