1,1-Bis(tert-butylperoxy)cyclohexane (HCID 76359)

개요

Organic solvent solution, added to lessen explosion hazard.

이름 및 식별자

우선 이름: 1,1-Bis(tert-butylperoxy)cyclohexane
IUPAC: 1,1-bis(tert-butylperoxy)cyclohexane
현지명: 1,1-디-(3차부틸퍼옥시)사이클로헥산
영어명: 1,1-Di(tert-butylperoxy)cyclohexane
분자식: C14H28O4
분자량: 260.37

이름 및 동의어

1,1-Bis(tert-butylperoxy)cyclohexane3006-86-8Cyclohexylidenebis(tert-butyl) peroxideUNII-JK62J3E3Q4JK62J3E3Q4EINECS 221-111-2PERHEXA CSLuperox 331M80Peroxide, 1,1'-cyclohexylidenebis(2-(1,1-dimethylethyl)EC 221-111-2PERHEXA C 40PERHEXA C 75

이름 더 보기

1,1-디-(3차부틸퍼옥시)사이클로헥산1,1-디-(터셔리-부틸퍼옥시)-싸이클로헥산1,1-디-(터셔리-부틸퍼옥시)-싸이클로헥산(57%이상)1,1-bis(T-butylperoxy)cyclohexaneDP275BPerhexa-CChaloxyd PTrigonox 22Lupersol 331TRIGONOX(R) 22Luperox? 331P80

PEROXAN PK 122WTRIGONOX 22C50TRIGONOX 22E50TRIGONOX 22E70LUPEROX 331DTXSID4044907TX 22E50Cyclohexylidenebis[tert-butyl] peroxide

데이터베이스 식별자

CAS: 3006-86-8
PubChem CID: 76359
DTXSID: DTXSID4044907
UNII: JK62J3E3Q4
EC Number: 221-111-2
Nikkaji: J4.394J

물성

구조 계산 물성

XLogP: 3.7
극성 표면적: 36.9 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 4
회전 가능 결합 수: 6
무거운 원자 수: 18
형식 전하: 0
복잡도: 224

실험 및 물리화학적 성질

Physical Description · 3건

Organic solvent solution, added to lessen explosion hazard.

Particularly heat and contamination sensitive.

CBI; Liquid

물리화학적 성질

녹는점: 65 °C · 65 °C (SADT)
끓는 점: 52 · 52-54 °C (0.1 mmHg)
밀도: 0.891 g/mL · 0.891 g/mL at 25 °C
증기압: 4.88 hPa · 4.88hPa at 25℃
굴절률: 20 · n20/D 1.435
인화점: 155 °F · 155 °F
저장 조건: 2 · 2-8°C
물리적 상태: 액체
색상: 투명한
수용성: 혼용 가능
InChI: InChI=1S/C14H28O4/c1-12(2,3)15-17-14(10-8-7-9-11-14)18-16-13(4,5)6/h7-11H2,1-6H3
InChIKey: HSLFISVKRDQEBY-UHFFFAOYSA-N
SMILES: C1(CCCCC1)(OOC(C)(C)C)OOC(C)(C)C
LogP: 7.2 at · 7.2 at 25℃
EPA: 1 · Peroxide, 1,1'-cyclohexylidenebis[2-(1,1-dimethylethyl) (3006-86-8)

화학적 성질

clear liquid

안전 및 규제

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 1.8% (3 of 170) of reports.

Danger

H242 (74.7%): Heating may cause a fire [Danger Self-reactive substances and mixtures; Organic peroxides]

P210, P234, P235, P240, P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403, P403+P233, P405, P410, P411, P420, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 170 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

유해성 정보

Regulatory Information · 4건

Chemical: Peroxide, cyclohexylidenebis[(1,1-dimethylethyl)

Peroxide, 1,1'-cyclohexylidenebis[2-(1,1-dimethylethyl) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Peroxide, 1,1'-cyclohexylidenebis[2-(1,1-dimethylethyl) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 15-05-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/5875

Peroxide, cyclohexylidenebis(1,1-dimethylethyl): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

DOT Label · 4건

Organic Peroxide

Organic Peroxide Explosive

Fire Hazards · 4건

Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:

Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:

Health Hazards · 4건

Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:

Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:

Reactive Group · 4건

Peroxides, Organic

Reactivity Alerts · 4건

Strong Oxidizing Agent

Explosive

Reactivity Profile · 4건

The explosive instability of the lower dialkyl peroxides (e.g., dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. It is unlikely that this derivative would be particularly unstable compared to other peroxides in its class. [Bretherick 2nd ed., p 44 1979.]

The explosive instability of the lower dialkyl peroxides (e.g.,. dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. It is unlikely that this derivative would be particularly unstable compared to other peroxides in its class. [Bretherick 2nd ed., p 44 1979.]

The explosive instability of the lower dialkyl peroxides (e.g., dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the mono functional peroxides. It is unlikely that this derivative would be particularly unstable compared to other peroxides in its class. [Bretherick 2nd ed., p 44 1979.]

안전 및 보호

Fire Fighting · 4건

Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:

Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:

First Aid · 4건

Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:

Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:

Nonfire Spill Response · 4건

Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:

Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:

Isolation and Evacuation · 4건

Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:

Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:

Personal Protective Equipment (PPE) · 4건

Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:

Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:

안전 데이터

wgk: 2
tsca: TSCA listed
ridadr: UN 3103 5.2
HS 번호: 29096000
risk_code: 7-62-50/53-36/37/38-61-65-45-51/53
hazard_code: O,N,T
safety_code: 17-36/37/39-3/7-14A-61-60-45-26-14-53-62
포장분류: II
위험 등급: 5.2
기존화학 물질: 2004-3-2858
Hazard Classifications: Asp. Tox. 1Carc. 1BEye Irrit. 2Muta. 1BOrg. Perox. CSkin Irrit. 2STOT SE 3
스토리지 클래스: 4.1A - Other explosive hazardous materials

화학 및 산업

용도 및 제조

U.S. Production2023: 1,000,000 - <2,500,000 lb

Consumer UsesNot Known or Reasonably Ascertainable

Industry UsesCBI

General Manufacturing Information · 2건

Plastics Material and Resin Manufacturing

Peroxide, 1,1'-cyclohexylidenebis[2-(1,1-dimethylethyl): ACTIVE

응용 분야

용도Polymerization initiator.

공급사50 곳

阿诺西（上海）生物技术有限公司400-1107768 15058188853 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]

Career Henan Chemica Co+86-0371-86658258 +86-13203830695 · [email protected]

湖北鑫杰成化工科技有限公司13554075426 · [email protected]

추가 설명

정의1,1-Di (tert-butylperoxy) cyclohexane (DTBPH) is a commercial liquid organic peroxide that is to be in aliphatic hydrocarbon solvent and transported and stored under limited temperature[1].