Allyl chloride → Trichloro(2,4,4-trimethylpentyl)silane

HRID 1680910

반응식

[Cl:1][SiH:2]([Cl:4])[Cl:3].[CH3:5][C:6]([CH2:8][C:9]([CH3:12])([CH3:11])[CH3:10])=[CH2:7].CC(C)=CC(C)(C)C.C(Cl)C=C>>[CH3:5][CH:6]([CH2:8][C:9]([CH3:12])([CH3:11])[CH3:10])[CH2:7][Si:2]([Cl:4])([Cl:3])[Cl:1]

참가 물질

반응물 4

HCID 7850Allyl chloride

HCID 78682,4,4-Trimethyl-1-pentene2회

HCID 78692,4,4-Trimethyl-2-pentene

HCID 24811Trichlorosilane3회

생성물 1

HCID 86714Trichloro(2,4,4-trimethylpentyl)silane

실험 절차

The process described in Example 2 is repeated, except that 1.2 liters of trichlorosilane, 1.8 liters of diisobutylene (a mixture of 2,4,4-trimethylpentene-1 and 2,4,4-trimethylpentene-2) and 10 ml of the catalytic solution are substituted for the trichlorosilane, allyl chloride and catalytic solution. About 98.6 mol percent of the trichlorosilane employed is reacted and 11.6 moles per hour of 2,4,4-trimethylpentyltrichlorosilane are obtained.

출처 및 근거

ORD 기록: ord-b643a7355bf94b5bb75ce21e901fbfa5
출처 데이터셋: uspto-grants-1981_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04276426

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