Hydrochloric Acid → 3-Methoxy-5-Methylphenol

HRID 1681447

반응식

[CH3:1][O:2][C:3]1[CH:4]=[C:5]([OH:14])[C:6](=[C:11]([CH3:13])[CH:12]=1)C(OC)=O.[OH-].[K+].Cl>>[CH3:1][O:2][C:3]1[CH:4]=[C:5]([OH:14])[CH:6]=[C:11]([CH3:13])[CH:12]=1

참가 물질

반응물 3

HCID 313Hydrochloric Acid

HCID 14797Potassium Hydroxide

HCID 596344Sparassol

생성물 1

HCID 766743-Methoxy-5-Methylphenol수율 70%

실험 절차

1.0 g of the methyl 4-methoxy-6-methyl-salicylate thus obtained is boiled under reflux with 35 ml of aqueous potassium hydroxide solution (15% strength) for 8 hours. The reaction mixture is then acidified with dilute hydrochloric acid and extracted with ethyl acetate. 0.70 g (yield: 70%) of orcinyl (3-methoxy-5-methylphenol) is obtained.

후처리

extractionextracted with ethyl acetate

출처 및 근거

ORD 기록: ord-a6b5fd3f4a044f499e59b76bc9063232
출처 데이터셋: uspto-grants-1992_12
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05171878

연결된 노트

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