Palladium Chloride → Palladium triflate

HRID 1682776노트

반응식

HRID 1682776 반응식
Cl[Pd:2]Cl.[OH:4][S:5]([C:8]([F:11])([F:10])[F:9])(=[O:7])=[O:6]>C(Cl)Cl>[O-:7][S:5]([C:8]([F:11])([F:10])[F:9])(=[O:6])=[O:4].[Pd+2:2].[O-:7][S:5]([C:8]([F:11])([F:10])[F:9])(=[O:6])=[O:4]

참가 물질

4

반응물 2

HCID 24290Palladium ChlorideHCID 62406Trifluoromethanesulfonic acid

생성물 1

HCID 11603820Palladium triflate

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

PdCl2 (1.0 g, 5.6 mmol) was slurried in CH2Cl2 (20 mL) and triflic acid (1.7 g, 11.3 mmol) was added dropwise. The mixture was stirred at room temperature overnight. The solvent was removed and 0.9 g of rust color solid was collected. 19F NMR (CDCl3): δ-5 78.5.

후처리

  1. customThe solvent was removed
  2. custom0.9 g of rust color solid was collected

출처 및 근거

ORD 기록
ord-f53ff08b482544a3899a442bed6f5ef3
출처 데이터셋
uspto-grants-1997_06
특허 번호
US05635585

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