Hydrochloric Acid → 5-Nitro-indan-2-ylamine hydrochloride

반응식

C([NH:4][CH:5]1[CH2:13][C:12]2[C:7](=[CH:8][CH:9]=[C:10]([N+:14]([O-:16])=[O:15])[CH:11]=2)[CH2:6]1)(=O)C.[ClH:17]>>[ClH:17].[N+:14]([C:10]1[CH:11]=[C:12]2[C:7](=[CH:8][CH:9]=1)[CH2:6][CH:5]([NH2:4])[CH2:13]2)([O-:16])=[O:15]

참가 물질

반응물 2

HCID 313Hydrochloric Acid

HCID 14820512N-(5-nitro-indan-2-yl)-acetamide

생성물 1

HCID 223193245-Nitro-indan-2-ylamine hydrochloride

실험 절차

N-Acetyl-5-nitro-2-indanamine, 1.5 g. (0.007 mole) as prepared in Example 9 was refluxed in 10% hydrochloric acid for 3 hours. The mixture was evaporated and the crystalline residue recrystallized from methanol-ether to yield 5-nitro-2-indanamine hydrochloride, dec.>280° C.

후처리

custom(0.007 mole) as prepared in Example 9
customThe mixture was evaporated
customthe crystalline residue recrystallized from methanol-ether

출처 및 근거

ORD 기록: ord-00640c1748ab49b6be035facddf7563e
출처 데이터셋: uspto-grants-1980_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04192888

반응 노트

불러오는 중…