Methane → HCID 131712825, 화합물

HRID 1702834

반응식

HRID 1702834 반응식
[Cl:1][C:2]1[C:11]([CH3:12])=[N:10][C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[N:3]=1.C.[NH2:14][C:15]([NH2:17])=[S:16]>CC(C)=O>[ClH:1].[CH3:12][C:11]1[C:2]([S:16][C:15](=[NH:14])[NH2:17])=[N:3][C:4]2[C:9]([N:10]=1)=[CH:8][CH:7]=[CH:6][CH:5]=2

참가 물질

5

반응물 3

HCID 297MethaneHCID 2362762-Chloro-3-methylquinoxalineHCID 2723790Thiourea

생성물 1

HCID 131712825HCID 131712825, 화합물

시약·촉매·용매 1

HCID 180Acetone용매2회

실험 절차

2-Chloro-3-methylquinoxaline (10.72 g., 0.06 mole) was dissolved in 150 ml. of acetone, treated with Norit and filtered. The filtrate was added to 4.56 g. (0.06 mole) of thiourea in 150 ml. acetone. The solution was stirred at reflux under nitrogen for 2 hours. The precipitate which began to form after 5 minutes, was filtered while the reaction mixture was hot. The solid was collected, washed with hot acetone and dried to give 11.85 g. of a pink solid, m.p. 156°-157° C.

후처리

  1. filtrationfiltered
  2. additionThe filtrate was added to 4.56 g
  3. temperatureat reflux under nitrogen for 2 hours
  4. customto form after 5 minutes
  5. filtrationwas filtered while the reaction mixture
  6. customThe solid was collected
  7. washwashed with hot acetone
  8. customdried
  9. customto give 11.85 g

출처 및 근거

ORD 기록
ord-4f4a18a7a7104b0787f29fc49657dc86
출처 데이터셋
uspto-grants-1982_09
특허 번호
US04349674

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