Hydrochloric Acid → (4-Decylphenyl)methanol

HRID 1703111노트

반응식

HRID 1703111 반응식
B.[CH2:2]([C:12]1[CH:20]=[CH:19][C:15]([C:16](O)=[O:17])=[CH:14][CH:13]=1)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].Cl>O1CCCC1>[CH2:2]([C:12]1[CH:13]=[CH:14][C:15]([CH2:16][OH:17])=[CH:19][CH:20]=1)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]

참가 물질

5

반응물 3

HCID 313Hydrochloric AcidHCID 6331BoraneHCID 123614764-Decylbenzoic acid

생성물 1

HCID 13079698(4-Decylphenyl)methanol

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매2회

실험 절차

To 69.5 ml. of 1 molar borane in tetrahydrofuran chilled in an ice bath is added dropwise over 40 minutes a solution of 17.2 g. of p-decylbenzoic acid in 150 ml. of dry tetrahydrofuran. The mixture is refluxed for 3.5 hours, chilled, 5 ml. of concentrated hydrochloric acid is added and the mixture poured onto ice. The mixture is filtered and the solid washed with water to give white crystals.

후처리

  1. additionis added dropwise over 40 minutes a solution of 17.2 g
  2. temperatureThe mixture is refluxed for 3.5 hours
  3. temperaturechilled
  4. additionthe mixture poured onto ice
  5. filtrationThe mixture is filtered
  6. washthe solid washed with water
  7. customto give white crystals

출처 및 근거

ORD 기록
ord-76f58722c44044cf98d0d5129f6d3350
출처 데이터셋
uspto-grants-1982_09
특허 번호
US04350822

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