Benzyl mercaptan → HCID 54092293, 화합물

HRID 1704274노트

반응식

HRID 1704274 반응식
[Cl:1][C:2]([F:10])=[CH:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]Cl.[CH2:11]([SH:18])[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1.[H-].[Na+]>CN(C)C=O>[Cl:1][C:2]([F:10])=[CH:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][S:18][CH2:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1

참가 물질

5

반응물 3

HCID 7509Benzyl mercaptanHCID 24758Sodium hydrideHCID 54070391HCID 54070391, 화합물

생성물 1

HCID 54092293HCID 54092293, 화합물수율 63.3%

시약·촉매·용매 1

HCID 6228Dimethylformamide용매

실험 절차

Operating as described in Example 10, from 3 g of 1,7-dichloro-1-fluoro-hept-1-ene, 2.14 g of benzylmercaptan, 0.7 g of NaH (at 55% concentration in paraffin oil) and 30 ml of N,N-dimethylformamide there were obtained 2.8 g of product which was purified in a chromatography column.

출처 및 근거

ORD 기록
ord-ad19e95ffd084be9bb6233e20b6c1ef9
출처 데이터셋
uspto-grants-1978_11
특허 번호
US04126623

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