Piperonal → HCID 86737060, 화합물

HRID 1706848노트

반응식

HRID 1706848 반응식
[CH:1]1[C:6]([CH:7]=O)=[CH:5][C:4]2[O:9][CH2:10][O:11][C:3]=2[CH:2]=1.[C:12]([N:17]1[CH2:22][CH2:21][CH2:20][CH2:19][CH2:18]1)(=[O:16])/[CH:13]=[CH:14]/[CH3:15].[OH-].C([N+](CC)(CC)CC1C=CC=CC=1)C>>[CH:7](=[CH:15]/[CH:14]=[CH:13]/[C:12]([N:17]1[CH2:22][CH2:21][CH2:20][CH2:19][CH2:18]1)=[O:16])[C:6]1[CH:1]=[CH:2][C:3]2[O:11][CH2:10][O:9][C:4]=2[CH:5]=1

참가 물질

4

반응물 3

HCID 8438PiperonalHCID 74601Benzyltriethylammonium hydroxideHCID 53724133626-69-5

생성물 1

HCID 86737060HCID 86737060, 화합물

실험 절차

1 mol of piperonal is reacted with 1.1 mols of crotonic acid piperidide in the presence of 0.09 mol of triethylbenzylammonium hydroxide in 100 parts by volume of one of the solvents indicated in Table 3 which follows, under the conditions described in Example 1 to give piperonylidenecrotonic acid piperidide. The yields achieved are likewise indicated in Table 3.

출처 및 근거

ORD 기록
ord-15e7becdbe0e4ebcbe34eaf13385f276
출처 데이터셋
uspto-grants-1980_06
특허 번호
US04209445

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