참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Phosphorus sulfide (P2S5) | HCID 14817 | — |
| 반응물 | Tetraphosphorus nonasulfide | HCID 141172 | — |
| 반응물 | 1-Cyano-1-hydroxy-1-(4-isobutylphenyl)ethane | HCID 15628327 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | 2-(4-Isobutylphenyl)propiononitrile | HCID 108374 | — |
| 생성물 | 2-(4-Isobutylphenyl)acrylonitrile | HCID 13227708 | — |
반응 단계
A crude solution of 410 mg (2.0 mmol) of 1-cyano-1-hydroxy-1-(4-isobutylphenyl)ethane (IBACH) in 5 mL of toluene was treated under nitrogen with 450 mg (1.0 mmol) of a finely-ground commercial phosphorus pentasulfide which is a mixture of tetraphosphorus decasulfide and tetraphosphorus nonasulfide. The reaction mixture was stirred well and heated in an 85° C. bath for one hour. GC analysis of the crude reaction product indicated that the reaction resulted in the formation of 1-cyano-1-(4-isobutylphenyl)ethane (PN) and 2-(4-isobutylphenyl)acrylonitrile (UN) in a ratio of 2/1.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04952718 |
|---|
| 출처 데이터셋 | uspto-grants-1990_08 |
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| ORD ID | ord-73bc2067b2d44290b2659aad313c6a6a |
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| 출처 메모 | uspto-grants-1990_08 |
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