1,4-Dimethoxybenzene → 2,2,3,4,4,4-Hexafluorobutyl methacrylate

HRID 1719194노트

반응식

HRID 1719194 반응식
[C:1](Cl)(=[O:5])[C:2]([CH3:4])=[CH2:3].[F:7][C:8]([F:17])([CH:11]([F:16])[C:12]([F:15])([F:14])[F:13])[CH2:9][OH:10].COC1C=CC(OC)=CC=1>>[C:1]([O:10][CH2:9][C:8]([F:17])([F:7])[CH:11]([F:16])[C:12]([F:15])([F:13])[F:14])(=[O:5])[C:2]([CH3:4])=[CH2:3]

참가 물질

4

반응물 3

HCID 90161,4-DimethoxybenzeneHCID 13528Methacryloyl chlorideHCID 5339902,2,3,4,4,4-Hexafluorobutan-1-ol

생성물 1

HCID 5497722,2,3,4,4,4-Hexafluorobutyl methacrylate

실험 절차

To 12 parts of methacrylic acid chloride were added 60 parts of 2,2,3,4,4,4-hexafluorobutyl alcohol as a reactant and a solvent and 0.1 part of hydroquinone dimethyl ether as a polymerization inhibitor. The mixture was heated at a temperature of 90° to 100° C. for 3 hours. The reaction mixture was distilled to give 15 parts of 2,2,3,4,4,4-hexafluorobutyl methacrylate (hereinafter referred to as "HFBMA") having a boiling point of 60° to 63° C./20 mmHg.

후처리

  1. temperatureThe mixture was heated at a temperature of 90° to 100° C. for 3 hours
  2. distillationThe reaction mixture was distilled

출처 및 근거

ORD 기록
ord-6cb724b71f6d4b05ab72ae5ebc16ab31
출처 데이터셋
uspto-grants-1985_09
특허 번호
US04539250

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