Sodium Hydroxide → 2-Methylanthraquinone

반응식

[OH-].[Na+].S([O-])(O)=O.[Na+].[CH3:8][C:9]1[C:10](=[O:20])[C:11]2[C:16]([C:17](=[O:19])[CH:18]=1)=[CH:15][CH:14]=[CH:13][CH:12]=2>>[CH3:10][C:9]1[CH:18]=[CH:8][C:9]2[C:10](=[O:20])[C:11]3[C:16](=[CH:15][CH:14]=[CH:13][CH:12]=3)[C:17](=[O:19])[C:18]=2[CH:8]=1

참가 물질

반응물 2

HCID 14798Sodium Hydroxide

HCID 236949362-Methyl-1,4-naphthoquinone sodium hydrogensulfite

생성물 1

HCID 67732-Methylanthraquinone

실험 절차

A 0.5N aqueous sodium hydroxide solution was added to the oil phase obtained in Example 14, and, after 30 minutes stirring, air was blown thereinto at 70° C. for 2 hours. Then, the oil phase and the aqueous phase containing the precipitate were separated, and the aqueous phase was dried under reduced pressure to obtain 5.5 kg of 2-methylanthraquinone.

후처리

waitat 70° C. for 2 hours
additionThen, the oil phase and the aqueous phase containing the precipitate
customwere separated
customthe aqueous phase was dried under reduced pressure

출처 및 근거

ORD 기록: ord-8413aed7ab6d412189a9f71f8dc2eb86
출처 데이터셋: uspto-grants-1994_07
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05329026

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