9,10-Anthracenedione, 1,2-dinitro- → 1-(p-Tert.-butyl-anilino)-6-nitro-anthraquinone

HRID 1729568

반응식

HRID 1729568 반응식
[N+:1]([C:4]1[C:17]2[C:16](=[O:18])[C:15]3[C:10](=[CH:11][C:12]([N+:19]([O-:21])=[O:20])=[CH:13][CH:14]=3)[C:9](=[O:22])[C:8]=2[CH:7]=[CH:6][CH:5]=1)([O-])=O.[C:23]([C:27]1[CH:33]=[CH:32][C:30](N)=[CH:29][CH:28]=1)([CH3:26])([CH3:25])[CH3:24].[N+](C1C=CC2C(=O)C3C(=CC=CC=3)C(=O)C=2C=1[N+]([O-])=O)([O-])=O>COCCO>[C:23]([C:27]1[CH:33]=[CH:32][C:30]([NH:1][C:4]2[C:17]3[C:16](=[O:18])[C:15]4[C:10](=[CH:11][C:12]([N+:19]([O-:21])=[O:20])=[CH:13][CH:14]=4)[C:9](=[O:22])[C:8]=3[CH:7]=[CH:6][CH:5]=2)=[CH:29][CH:28]=1)([CH3:26])([CH3:25])[CH3:24]

참가 물질

5

반응물 3

HCID 425969,10-Anthracenedione, 1,2-dinitro-HCID 698614-Tert-ButylanilineHCID 741461,6-Dinitroanthraquinone

생성물 1

HCID 203164881-(p-Tert.-butyl-anilino)-6-nitro-anthraquinone

시약·촉매·용매 1

HCID 80192-Methoxyethanol용매

실험 절차

The product employed in a) can be obtained as follows: 15 g of 1,6-dinitro-anthraquinone and 30 ml of p-tert.-butylaniline are stirred at 125° C until no further dinitro-anthraquinone is detectable (approx. 6 hours being required). The warm mixture is diluted with 30 ml of ethylene glycol monomethyl ether, stirred until cold and filtered, and the residue is successively washed with ethylene glycol monomethyl ether and water. 13.9 g of 1-(p-tert.-butyl-anilino)-6-nitro-anthraquinone are obtained.

후처리

  1. customcan be obtained
  2. custom(approx. 6 hours being required)
  3. filtrationfiltered
  4. washthe residue is successively washed with ethylene glycol monomethyl ether and water

출처 및 근거

ORD 기록
ord-9de4435a2650493ea834b75ac03efc9b
출처 데이터셋
uspto-grants-1976_11
특허 번호
US03989450

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