Ethanol → HCID 178524964, 화합물
반응식
[Na:1].C(O)C.[NH2:5][C:6]1[S:10][N:9]=[N:8][C:7]=1[C:11]([O:13]CC)=[O:12]>O>[Na:1].[Na:1].[Na:1].[C:11]([C:7]1[N:8]=[N:9][NH:5][C:6]=1[SH:10])([OH:13])=[O:12]참가 물질
5
실험 절차
To a solution of 4.6 g. (0.20 mol.) of sodium and 250 ml. of absolute ethanol was added under a nitrogen atmosphere 8.65 g. (0.05 mol.) of 5-amino-4-carbethoxy-1,2,3-thiadiazole. The reaction mixture was stirred 1 hour, 5 ml. of water was added and the mixture was refluxed for 12 hours. After cooling, the mixture was filtered and the solid product was washed with ethanol and ether and dried to give 4-carboxy-1,2,3-triazole-5-thiol trisodium salt.
후처리
- temperaturethe mixture was refluxed for 12 hours
- temperatureAfter cooling
- filtrationthe mixture was filtered
- washthe solid product was washed with ethanol and ether
- customdried
출처 및 근거
- ORD 기록
- ord-35f887ffcbc54038b88640bde829eecc
- 출처 데이터셋
- uspto-grants-1976_11
- 특허 번호
- US03989694
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