Propan-2-ylcarbamyl chloride → Carbamic chloride

HRID 1730099노트

반응식

HRID 1730099 반응식
[CH:1]([NH:4][C:5]([Cl:7])=[O:6])([CH3:3])[CH3:2]>ClC1C=CC=CC=1>[CH:1]([N:4]=[C:5]=[O:6])([CH3:3])[CH3:2].[C:5]([Cl:7])(=[O:6])[NH2:4]

참가 물질

4

반응물 1

HCID 12681864Propan-2-ylcarbamyl chloride

생성물 2

HCID 61277Isopropyl isocyanateHCID 68048Carbamic chloride수율 93%

시약·촉매·용매 1

HCID 7964Chlorobenzene용매

실험 절차

A solution of 970 parts of isopropylcarbamic acid chloride in 1,020 parts of chlorobenzene is inroduced into an apparatus analogous to that of Example 1 and is refluxed for 9 hours -- during which the reaction temperature rises from 77° to 88° C -- whilst passing 120,000 parts by volume of dry nitrogen per hour through the mixture. The subsequent distillation gives 630 parts of isopropyl isocyanate free from carbamic acid chloride (corresponding to 93% of theory, based on isopropylcarbamic acid chloride used), boiling at from 73.5° to 74.5° C.

후처리

  1. temperatureis refluxed for 9 hours
  2. customrises from 77° to 88° C
  3. distillationThe subsequent distillation

출처 및 근거

ORD 기록
ord-f344c4760e4341239ed1ed0e958aa602
출처 데이터셋
uspto-grants-1976_11
특허 번호
US03991094

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