반응식
[F:1][CH:2]([F:13])[O:3][C:4]1[CH:12]=[CH:11][C:7]([C:8]([OH:10])=[O:9])=[CH:6][CH:5]=1.C1C(CO)=CC=C(O)C=1.[Mn]([O-])(=O)(=O)=O.[K+].[CH2:29]([C@H:32]1[CH2:37][CH2:36][C@H:35]([C:38]2[CH:43]=[CH:42][C:41](O)=[CH:40][CH:39]=2)[CH2:34][CH2:33]1)[CH2:30][CH3:31].C1CCC(N=C=NC2CCCCC2)CC1>>[F:1][CH:2]([F:13])[O:3][C:4]1[CH:5]=[CH:6][C:7]([C:8]([O:10][C:41]2[CH:40]=[CH:39][C:38]([C@H:35]3[CH2:36][CH2:37][C@H:32]([CH2:29][CH2:30][CH3:31])[CH2:33][CH2:34]3)=[CH:43][CH:42]=2)=[O:9])=[CH:11][CH:12]=1참가 물질
6
실험 절차
4-Difluoromethoxybenzoic acid (available by etherification of the phenolic OH group of p-hydroxybenzyl alcohol analogously to Example 1a), followed by oxidation with potassium permanganate) is esterified, as described in Example 5b), with 4-(trans-4-propylcyclohexyl)-phenol by the DCC method. m.p.: 104° C., c.p.: 193.5° C.
후처리
- custom193.5° C.
출처 및 근거
- ORD 기록
- ord-e950a02c81234aa7bab72eb305b3fbc6
- 출처 데이터셋
- uspto-grants-1996_07
- 특허 번호
- US05536442
연결된 노트
불러오는 중…