(4-Benzoyl-2-nitro-phenyl)-carbamic acid tert.-butyl ester → Carbamic acid,(2-amino-4-benzoylphenyl)-,1,1-dimethylethyl ester
반응식
[C:1]([O:5][C:6](=[O:25])[NH:7][C:8]1[CH:13]=[CH:12][C:11]([C:14](=[O:21])[C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)=[CH:10][C:9]=1[N+:22]([O-])=O)([CH3:4])([CH3:3])[CH3:2]>[Ni]>[C:1]([O:5][C:6](=[O:25])[NH:7][C:8]1[CH:13]=[CH:12][C:11]([C:14](=[O:21])[C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)=[CH:10][C:9]=1[NH2:22])([CH3:4])([CH3:2])[CH3:3]참가 물질
3
실험 절차
Prepared from (4-benzoyl-2-nitro-phenyl)-carbamic acid tert.-butyl ester (Example D1) (280 mg, 0.82 mmol) by catalytic hydrogenation with Raney-Ni according to the general procedure G (method a). Obtained as a yellow foam (269 mg).
출처 및 근거
- ORD 기록
- ord-dac6d1a7682147a9aa6fdbe697c14ffd
- 출처 데이터셋
- uspto-grants-2006_03
- 특허 번호
- US07018998B2
반응 노트
불러오는 중…