Potassium Permanganate → 1,2,3-Benzenetricarboxylic acid

HRID 1751905

반응식

HRID 1751905 반응식
[Na+].[Na+].C([O:5][CH2:6][C:7]1[CH:15]=[CH:14][CH:13]=[C:9]([C:10]([O-:12])=[O:11])[C:8]=1[C:16]([O-:18])=[O:17])C.[Mn]([O-])(=O)(=O)=[O:20].[K+]>O>[C:6]([OH:5])(=[O:20])[C:7]1[CH:15]=[CH:14][CH:13]=[C:9]([C:10]([OH:12])=[O:11])[C:8]=1[C:16]([OH:18])=[O:17]

참가 물질

4

반응물 2

HCID 516875Potassium PermanganateHCID 89479305HCID 89479305, 화합물

생성물 1

HCID 112881,2,3-Benzenetricarboxylic acid수율 42%

시약·촉매·용매 1

HCID 962Water용매

실험 절차

3-(Ethoxymethyl)phthalic acid disodium salt (3.7 mmol) from Example 2 was dissolved in water (40 ml). Potassium permanganate (7.5 mmol) was added and the resulting solution was stirred for 18 h at room temperature. The precipitate formed was filtered off and washed three times with hot water. The combined aqueous phase was evaporated under reduced pressure to approximately one third of the initial volume and cooled in an ice-bath. Concentrated HCl was added carefully for neutralization. The precipitated hemimellitic acid was collected on a glass filter, washed with water and dried (yield: 42%).

후처리

  1. customThe precipitate formed
  2. filtrationwas filtered off
  3. washwashed three times with hot water
  4. customThe combined aqueous phase was evaporated under reduced pressure to approximately one third of the initial volume
  5. temperaturecooled in an ice-bath
  6. additionConcentrated HCl was added carefully for neutralization
  7. customThe precipitated hemimellitic acid was collected on a glass
  8. filtrationfilter
  9. washwashed with water
  10. customdried (yield: 42%)

출처 및 근거

ORD 기록
ord-8829c82ae9a147888fdbc9d3b33f56f6
출처 데이터셋
uspto-grants-2015_10
특허 번호
US09162960B2

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