Hydrogen Peroxide → Di(trifluoroacetoxy)iodopentafluoroethane

HRID 1758175

반응식

HRID 1758175 반응식
FC(F)(F)C([O:5][C:6](=[O:11])[C:7]([F:10])([F:9])[F:8])=O.[F:14][C:15]([F:20])([F:19])[C:16]([OH:18])=[O:17].OO.[F:23][C:24]([I:30])([F:29])[C:25]([F:28])([F:27])[F:26]>>[F:14][C:15]([F:20])([F:19])[C:16]([O:18][I:30]([O:5][C:6](=[O:11])[C:7]([F:8])([F:9])[F:10])[C:24]([F:29])([F:23])[C:25]([F:28])([F:27])[F:26])=[O:17]

참가 물질

5

반응물 4

HCID 784Hydrogen PeroxideHCID 6422Trifluoroacetic acidHCID 9636IodopentafluoroethaneHCID 9845Trifluoroacetic anhydride

생성물 1

HCID 12918315Di(trifluoroacetoxy)iodopentafluoroethane수율 85%

실험 절차

To a mixture of 18.6 ml (132 mmols) of trifluoroacetic anhydride and 32 ml of trifluoroacetic acid was added dropwise 1.66 ml of a 30% aqueous hydrogen peroxide solution (H2O2, 16.3 mmols and H2O, 71.7 mmols) in an ice bath. After completion of the addition, the mixture was stirred for 3 hours and 0.90 ml (8.13 mmols) of pentafluoroethyl iodide was added thereto, followed by allowing the mixture to react at 0° to 5° C. for 24 hours. The solvent was then distilled off to obtain 3.3 g (85% yield) of di(trifluoroacetoxy)iodopentafluoroethane as a white fluffy crystals.

후처리

  1. additionAfter completion of the addition
  2. customto react at 0° to 5° C. for 24 hours
  3. distillationThe solvent was then distilled off

출처 및 근거

ORD 기록
ord-5c718ce20f4e4f229a4a6dcfb9e9f0af
출처 데이터셋
uspto-grants-1983_02
특허 번호
US04371710

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