Bisphenol A diglycidyl ether → 2,2-Bis{4-[2-hydroxy-3-(7,7,9,9-tetramethyl-1,4-dioxa-8-azaspiro[4.5]dec-8-yl)propoxy]phenyl}propane

HRID 1758194

반응식

HRID 1758194 반응식
[O:1]1[CH2:25][CH:2]1[CH2:3][O:4][C:5]1[CH:10]=[CH:9][C:8]([C:11]([C:14]2[CH:19]=[CH:18][C:17]([O:20][CH2:21][CH:22]3[O:24][CH2:23]3)=[CH:16][CH:15]=2)([CH3:13])[CH3:12])=[CH:7][CH:6]=1.[CH3:26][C:27]1([CH3:39])[NH:36][C:35]([CH3:38])([CH3:37])[CH2:34][C:29]2([O:33][CH2:32][CH2:31][O:30]2)[CH2:28]1>C(O)(C)(C)C>[OH:1][CH:2]([CH2:25][N:36]1[C:35]([CH3:38])([CH3:37])[CH2:34][C:29]2([O:30][CH2:31][CH2:32][O:33]2)[CH2:28][C:27]1([CH3:39])[CH3:26])[CH2:3][O:4][C:5]1[CH:6]=[CH:7][C:8]([C:11]([C:14]2[CH:15]=[CH:16][C:17]([O:20][CH2:21][CH:22]([OH:24])[CH2:23][N:36]3[C:27]([CH3:39])([CH3:26])[CH2:28][C:29]4([O:30][CH2:31][CH2:32][O:33]4)[CH2:34][C:35]3([CH3:38])[CH3:37])=[CH:18][CH:19]=2)([CH3:13])[CH3:12])=[CH:9][CH:10]=1

참가 물질

4

반응물 2

HCID 2286Bisphenol A diglycidyl etherHCID 5670457,7,9,9-Tetramethyl-1,4-dioxa-8-azaspiro[4.5]decane

생성물 1

HCID 205105972,2-Bis{4-[2-hydroxy-3-(7,7,9,9-tetramethyl-1,4-dioxa-8-azaspiro[4.5]dec-8-yl)propoxy]phenyl}propane

시약·촉매·용매 1

HCID 6386tert-Butanol용매

실험 절차

To 50 ml of t-butanol were added 3.5 g of 2,2-bis[p-(2,3-epoxypropoxy)phenyl]propane and 5.0 g of 7,7,9,9-tetramethyl-1,4-dioxa-8-azaspiro[4.5]decane; the mixture was then reacted following the procedure described in Example 21 to give the desired Compound No. 126 in the form of a white powder having an Rf value of 0.38 on thin-layer chromatography on silica gel developed with a 20:2:1 by volume mixture of benzene, ethyl acetate and triethylamine.

후처리

  1. customthe mixture was then reacted

출처 및 근거

ORD 기록
ord-13b75f9a175545c69335d2d73bc425a6
출처 데이터셋
uspto-grants-1983_02
특허 번호
US04371644

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