HCID 12094927, 화합물 → HCID 12094928, 화합물

HRID 1767761노트

반응식

HRID 1767761 반응식
[C:1]1([C:6]2[CH:7]=[C:8]([CH2:12][OH:13])[CH:9]=[CH:10][CH:11]=2)[CH2:5][CH2:4][CH2:3][CH:2]=1>O=[Mn]=O.C(Cl)(Cl)Cl>[C:1]1([C:6]2[CH:7]=[C:8]([CH:9]=[CH:10][CH:11]=2)[CH:12]=[O:13])[CH2:5][CH2:4][CH2:3][CH:2]=1

참가 물질

4

반응물 1

HCID 12094927HCID 12094927, 화합물

생성물 1

HCID 12094928HCID 12094928, 화합물수율 76.2%

시약·촉매·용매 2

HCID 14801Manganese dioxide촉매HCID 6212Chloroform용매

반응 조건

온도
60 °C

실험 절차

1.35 g (8 mmol) of (3-cyclopenten-1-ylphenyl)methanol (5a) and 80 ml of chloroform are introduced into a round-bottomed flask. 6.8 g of MnO2 are then added and the suspension is heated at 60° C. for 2 hours. The mixture is filtered in the hot state, the precipitate washed with chloroform and then the filtrate concentrated under reduced pressure. The title product (1.05 g) is obtained in the form of a yellow oil which is used in the next step without further purification.

후처리

  1. filtrationThe mixture is filtered in the hot state
  2. washthe precipitate washed with chloroform
  3. concentrationthe filtrate concentrated under reduced pressure

출처 및 근거

ORD 기록
ord-06e0fcc201664cecbf47d7ee60e08d85
출처 데이터셋
uspto-grants-2007_06
특허 번호
US07235568B2

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