Myristyl bromide → 1-(4-Chlorophenyl)-3-tetradecyl imidazolium bromide

HRID 1774334

반응식

HRID 1774334 반응식
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([N:8]2[CH:12]=[CH:11][N:10]=[CH:9]2)=[CH:4][CH:3]=1.[Br:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27]>C1COCC1>[Br-:13].[Cl:1][C:2]1[CH:3]=[CH:4][C:5]([N+:8]2[CH:12]=[CH:11][N:10]([CH2:27][CH2:26][CH2:25][CH2:24][CH2:23][CH2:22][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH3:14])[CH:9]=2)=[CH:6][CH:7]=1

참가 물질

4

반응물 2

HCID 8208Myristyl bromideHCID 1428591-(4-Chlorophenyl)-1H-imidazole

생성물 1

HCID 1784431521-(4-Chlorophenyl)-3-tetradecyl imidazolium bromide

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매

실험 절차

According to the general synthesis procedure 5.6 mmol (1.00 g) 1-(4-chlorophenyl)imidazole and 6.7 mmol (1.86 g, 1.82 ml) 1-bromotetradecane are dissolved in 5 ml THF and heated for 42 h to 90° C. At the end of the reaction the reaction mixture is cooled down to room temperature and the product is precipitated with diethylether.

후처리

  1. temperatureheated for 42 h to 90° C
  2. customAt the end of the reaction the reaction mixture
  3. customthe product is precipitated with diethylether

출처 및 근거

ORD 기록
ord-102dde7402434d619b8f589ac226a8b0
출처 데이터셋
uspto-grants-2016_02
특허 번호
US09260397B2

연결된 노트

불러오는 중…