Sodium hydride → 4-(3,6-Dimethoxyphenylsulphanyl)-2-amino-nitrobenzene

HRID 1795866

반응식

OC1C=CC(S[C:9]2[CH:14]=[CH:13][C:12]([N+:15]([O-:17])=[O:16])=[C:11]([NH2:18])[CH:10]=2)=CC=1.[H-].[Na+].[CH3:21][O:22][C:23]1[CH:24]=[C:25]([SH:31])[C:26]([O:29][CH3:30])=[CH:27][CH:28]=1>>[CH3:21][O:22][C:23]1[CH:24]=[C:25]([S:31][C:9]2[CH:14]=[CH:13][C:12]([N+:15]([O-:17])=[O:16])=[C:11]([NH2:18])[CH:10]=2)[C:26]([O:29][CH3:30])=[CH:27][CH:28]=1

참가 물질

반응물 3

HCID 24758Sodium hydride

HCID 5190092,5-Dimethoxythiophenol

HCID 221806834-(4-Hydroxyphenylsulphanyl)-2-amino-nitrobenzene

생성물 1

HCID 221807004-(3,6-Dimethoxyphenylsulphanyl)-2-amino-nitrobenzene

실험 절차

Using the general method described for 4-(4-hydroxyphenylsulphanyl)-2-amino-nitrobenzene in Example 2, except that one equivalent of NaH was used, 4-(3,6-dimethoxyphenylsulphanyl)-2-amino-nitrobenzene (4.19 g) was prepared from 3,6-dimethoxybenzenethiol (2.55 g; 15 mmol).

출처 및 근거

ORD 기록: ord-5c4db8bb278e4e6fa09fc86a1ca03b64
출처 데이터셋: uspto-grants-2006_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07030123B2

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