Diphenylamine → 4-Bromodiphenylamine

HRID 1805967

반응식

HRID 1805967 반응식
[C:1]1([NH:7][C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Br:14]N1C(=O)CCC1=O>C(OCC)(=O)C>[CH:11]1[CH:10]=[CH:9][C:8]([NH:7][C:1]2[CH:2]=[CH:3][C:4]([Br:14])=[CH:5][CH:6]=2)=[CH:13][CH:12]=1

참가 물질

4

반응물 2

HCID 11487DiphenylamineHCID 67184N-bromobutanimide

생성물 1

HCID 64257864-Bromodiphenylamine

시약·촉매·용매 1

HCID 8857Ethyl Acetate용매

실험 절차

In a 1-L conical flask, 51 g (0.3 mol) of diphenylamine was dissolved in 700 mL of ethyl acetate, and then 54 g (0.3 mol) of N-bromosuccinimide (abbreviation: NBS) was added to this solution. About 300 hours later, this mixture solution was washed with water, and then magnesium sulfate was added thereto to remove moisture. This mixture solution was filtered, the filtrate was concentrated, and the resulting substance was collected. Accordingly, a dark brown oily substance, which was the substance to be produced, was obtained, and the amount and yield of the substance were 70 g and 94%, respectively.

후처리

  1. washthis mixture solution was washed with water
  2. additionmagnesium sulfate was added
  3. customto remove moisture
  4. filtrationThis mixture solution was filtered
  5. concentrationthe filtrate was concentrated
  6. customthe resulting substance was collected
  7. customto be produced
  8. customwas obtained

출처 및 근거

ORD 기록
ord-230efc1e2f254f588457384f9fd7689a
출처 데이터셋
uspto-grants-2013_01
특허 번호
US08354542B2

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