Ammonium Acetate → 4-Aminospiro[5.5]undec-3-EN-2-one

HRID 1817808

반응식

CN(C)[C:3]1[CH:8]=[CH:7][C:6]([CH:9]2[CH2:14][C:13](=[O:15])[CH2:12][C:11](=O)[CH2:10]2)=C[CH:4]=1.C([O-])(=O)C.[NH4+:22]>>[NH2:22][C:11]1[CH2:10][C:9]2([CH2:4][CH2:3][CH2:8][CH2:7][CH2:6]2)[CH2:14][C:13](=[O:15])[CH:12]=1

참가 물질

반응물 2

HCID 517165Ammonium Acetate

HCID 7301175-(4-(Dimethylamino)phenyl)-1,3-cyclohexanedione

생성물 1

HCID 122101064-Aminospiro[5.5]undec-3-EN-2-one

실험 절차

In analogy to (Baraldi, P. G.; Simoni, D.; Manfredini, S.; Synthesis 1983, (11) 902-903) spiro[5.5]undecane-2,4-dione was reacted with ammonium acetate to give the title compound as a colorless solid.

출처 및 근거

ORD 기록: ord-755aae33288b46669bb9b7d070e48198
출처 데이터셋: uspto-grants-2009_10
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07598384B2

연결된 노트

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