2,4-Dimethylpent-2-ene → HCID 22129039, 화합물

HRID 1858396노트

반응식

HRID 1858396 반응식
[CH3:1][CH:2]([CH:4]=[C:5]([CH3:7])[CH3:6])[CH3:3].[Cl:8][SiH:9]([Cl:11])[Cl:10].N(C1(C#N)CCCCC1)=NC1(C#N)CCCCC1>>[CH3:6][CH:5]([CH:4]([Si:9]([Cl:11])([Cl:10])[Cl:8])[CH:2]([CH3:3])[CH3:1])[CH3:7]

참가 물질

4

반응물 3

HCID 122602,4-Dimethylpent-2-eneHCID 24811TrichlorosilaneHCID 749781,1'-Azobis(cyclohexanecarbonitrile)

생성물 1

HCID 22129039HCID 22129039, 화합물수율 89.3%

실험 절차

A one-liter autoclave equipped with a stirrer was charged in a nitrogen atmosphere with 55 grams (0.56 mol) of 2,4-dimethyl-3-pentene, 148 grams (1.1 mol) of trichlorosilane and 17 grams (70 mmols) of 1,1'-azobis(cyclohexane-1-carbonitrile) and the mixture was reacted at a temperature of 130° C. for 4 days. The resulting reaction mixture was purified by distillation thereby obtaining 117 grams (0.50 mol) of 2,4-dimethyl-3-trichlorosilylpentane. The structure of the resulting product was identified by 1HNMR.

후처리

  1. customA one-liter autoclave equipped with a stirrer
  2. customthe mixture was reacted at a temperature of 130° C. for 4 days
  3. customThe resulting reaction mixture
  4. distillationwas purified by distillation

출처 및 근거

ORD 기록
ord-18b16a5cd7f742419e33d5ce4be60108
출처 데이터셋
uspto-grants-2000_11
특허 번호
US06150549

반응 노트

불러오는 중…