2,3-Dinitrophenol → tert-Butyl-[2-(2,3-dinitro-phenoxy)-ethoxy]-dimethyl-silane

반응식

[N+:1]([C:4]1[C:9]([N+:10]([O-:12])=[O:11])=[CH:8][CH:7]=[CH:6][C:5]=1[OH:13])([O-:3])=[O:2].Br[CH2:15][CH2:16][O:17][Si:18]([C:21]([CH3:24])([CH3:23])[CH3:22])([CH3:20])[CH3:19]>>[C:21]([Si:18]([O:17][CH2:16][CH2:15][O:13][C:5]1[CH:6]=[CH:7][CH:8]=[C:9]([N+:10]([O-:12])=[O:11])[C:4]=1[N+:1]([O-:3])=[O:2])([CH3:20])[CH3:19])([CH3:24])([CH3:23])[CH3:22]

참가 물질

반응물 2

HCID 61912,3-Dinitrophenol

HCID 3608067(2-Bromoethoxy)-tert-butyldimethylsilane

생성물 1

HCID 86761134tert-Butyl-[2-(2,3-dinitro-phenoxy)-ethoxy]-dimethyl-silane

실험 절차

tert-Butyl-[2-(2,3-dinitro-phenoxy)-ethoxy]-dimethyl-silane was prepared by a procedure according to example 108 (i) starting from 500 mg (2.72 mmol) 2,3-dinitro-phenol and 1.00 g (4.18 mmol) (2-Bromo-ethoxy)-tert-butyl-dimethyl-silane.

출처 및 근거

ORD 기록: ord-b73f6b5a3bf445309b73cd318c889108
출처 데이터셋: uspto-grants-2010_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07741341B2

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