Carbon Tetrachloride → 1,3-Dichloro-5-(3,3-dichloro-allyloxy)-2-[3,3-dichloro-2-(4-trifluoromethyl-phenoxymethyl)-allyloxy]-benzene

HRID 1869147노트

반응식

HRID 1869147 반응식
C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.[C:20](Cl)(Cl)([Cl:22])[Cl:21].[Cl:25][C:26]1[CH:47]=[C:46]([O:48][CH2:49][CH:50]=[C:51]([Cl:53])[Cl:52])[CH:45]=[C:44]([Cl:54])[C:27]=1[O:28][CH2:29][C:30](=O)[CH2:31][O:32][C:33]1[CH:38]=[CH:37][C:36]([C:39]([F:42])([F:41])[F:40])=[CH:35][CH:34]=1>C(#N)C>[Cl:25][C:26]1[CH:47]=[C:46]([O:48][CH2:49][CH:50]=[C:51]([Cl:52])[Cl:53])[CH:45]=[C:44]([Cl:54])[C:27]=1[O:28][CH2:29][C:30]([CH2:31][O:32][C:33]1[CH:34]=[CH:35][C:36]([C:39]([F:42])([F:41])[F:40])=[CH:37][CH:38]=1)=[C:20]([Cl:22])[Cl:21]

참가 물질

5

반응물 3

HCID 5943Carbon TetrachlorideHCID 11776TriphenylphosphineHCID 86613082HCID 86613082, 화합물

생성물 1

HCID 866130861,3-Dichloro-5-(3,3-dichloro-allyloxy)-2-[3,3-dichloro-2-(4-trifluoromethyl-phenoxymethyl)-allyloxy]-benzene

시약·촉매·용매 1

HCID 6342Acetonitrile용매

실험 절차

312 mg of triphenylphosphine, 183 mg of carbon tetrachloride and 200 mg of 1-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-3-(4-trifluoromethyl-phenoxy)-propan-2-one are stirred in 3 ml of acetonitrile for 24 hours at 55° C. The reaction mixture is concentrated and the residue is purified over silica gel. The title compound is obtained.

후처리

  1. concentrationThe reaction mixture is concentrated
  2. customthe residue is purified over silica gel

출처 및 근거

ORD 기록
ord-7bae7ae803fa4315b91414a54d8fdc88
출처 데이터셋
uspto-grants-2009_12
특허 번호
US07638514B2

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