Diazomethane → Methyl-4-iodocinnamate

HRID 1869824노트

반응식

HRID 1869824 반응식
[I:1][C:2]1[CH:12]=[CH:11][C:5]([CH:6]=[CH:7][C:8]([OH:10])=[O:9])=[CH:4][CH:3]=1.[N+](=[CH2:15])=[N-]>CO.C(OCC)C>[CH3:15][O:9][C:8](=[O:10])[CH:7]=[CH:6][C:5]1[CH:4]=[CH:3][C:2]([I:1])=[CH:12][CH:11]=1

참가 물질

5

반응물 2

HCID 9550DiazomethaneHCID 35997884-Iodocinnamic acid

생성물 1

HCID 582796Methyl-4-iodocinnamate

시약·촉매·용매 2

HCID 887Methanol용매HCID 3283Diethyl Ether용매

실험 절차

A stirred, cooled (ice bath) solution of 4-iodo-cinnamic acid in methanol was treated with a solution of diazomethane in diethyl ether. The reaction mixture was allowed to warm to ambient temperature, the volatiles were evaporated in vacuo to afford the title compound.

후처리

  1. customthe volatiles were evaporated in vacuo

출처 및 근거

ORD 기록
ord-42cf8e4d98564c9a94dbd28a55a7d7ba
출처 데이터셋
uspto-grants-2009_12
특허 번호
US07638648B2

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