Fructose 6-phosphate → 2,5-anhydro-D-mannitol

HRID 1885828

반응식

[OH:1][CH:2]1[O:10][C@H:9]([CH2:11][OH:12])[C@@H:7]([OH:8])[C@H:5]([OH:6])[C@H:3]1N.P(OC[C@@H](O)[C@@H](O)[C@H](O)C(=O)CO)(O)(O)=O>>[CH2:11]([OH:12])[C@H:9]1[O:10][C@H:3]([CH2:2][OH:1])[C@@H:5]([OH:6])[C@@H:7]1[OH:8]

참가 물질

반응물 2

HCID 69507Fructose 6-phosphate

HCID 439213D-Glucosamine

생성물 1

HCID 735442,5-anhydro-D-mannitol

실험 절차

D-mannitol was obtained commercially (Pfanstiehl Laboratories, Waukegan, IL). 2,5-anhydro-D-mannitol was prepared by deamination and reduction of D-glucosamine according to a known procedure of Bera, D. C., Foster, A. B. and Stacey, N., J. Chem. Soc. (1956) p. 4531-4541. The fructose 6-phosphate site of phosphofructokinase. J. Biol. Chem. (1974) 249:5749-5754.

출처 및 근거

ORD 기록: ord-57ec3fc277114cdf99197176c55a952d
출처 데이터셋: uspto-grants-1992_09
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05147776

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