Saccharin → Glycidyl methacrylate

HRID 1904173

반응식

HRID 1904173 반응식
C(N=C(N)N)#N.ClC1C=C(NC(N(C)C)=[O:17])C=CC=1C.[C:21]([O:30]OC(C)(C)C)([C:24]1[CH:29]=CC=C[CH:25]=1)(C)C.CN(C)C1C=CC(C)=CC=1.C1C=[C:50]2[C:52](NS(=O)(=O)[C:49]2=CC=1)=[O:53].P(NN)(=O)(OCC)OCC>>[C:21]([O:30][CH2:49][CH:50]1[O:53][CH2:52]1)(=[O:17])[C:24]([CH3:25])=[CH2:29]

참가 물질

7

반응물 6

HCID 5143SaccharinHCID 7471Dimethyl-p-toluidineHCID 10005DicyandiamideHCID 27375ChlortoluronHCID 76997Tert-butyl cumene peroxideHCID 143340Phosphorohydrazidic acid, diethyl ester

생성물 1

HCID 7837Glycidyl methacrylate

실험 절차

Mixture A (20.0 g) is mixed with dicyandiamide (0.4 g) and N-(3-chloro-4-methylphenyl)-N',N'-dimethylurea (0.4 g) and the mixture milled in a triple-roll mill until homogeneous. The milled product is then treated with tert.butyl cumyl peroxide (0.5 g), N,N-dimethyl-p-toluidine (0.1 g), o-benzoic sulphimide (0.1 g) and diethyl phosphoro hydrazidate (0.2 g) and mixed until homogeneous.

후처리

  1. customthe mixture milled in a triple-roll mill until homogeneous
  2. additionmixed until homogeneous

출처 및 근거

ORD 기록
ord-b792ab895cad43c9a0eeda076231395e
출처 데이터셋
uspto-grants-1989_06
특허 번호
US04836878

연결된 노트

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