Trichlorosilane → Trichloro(1,4-dichlorobut-2-en-2-yl)silane

HRID 1904347노트

반응식

HRID 1904347 반응식
[Cl:1][C:2]#[C:3][CH2:4][CH2:5][Cl:6].[Cl:7][SiH:8]([Cl:10])[Cl:9]>C(O)(C)C>[Cl:1][CH2:2][C:3]([Si:8]([Cl:10])([Cl:9])[Cl:7])=[CH:4][CH2:5][Cl:6]

참가 물질

4

반응물 2

HCID 24811TrichlorosilaneHCID 550741,4-Dichloro-1-butyne

생성물 1

HCID 53421800Trichloro(1,4-dichlorobut-2-en-2-yl)silane수율 94%

시약·촉매·용매 1

HCID 3776Isopropanol용매

실험 절차

To a mixed solution of 15 ml (0.153 mol) of 1,4-dichloro-1-butyne [IV]and 13.6 ml (0.16 mol) of trichlorosilane (bp: 31°-32° C.) [V], were added 0.15 ml (10 mmol) of H2PtCl6 . 6H2O in an isopropyl alcohol solution (0.05 g/ml), which were heated for 8 hours. Then, it was directly distillated to obtain 37 g of 1,4-dichloro-2-(trichloro)silyl-2-butene [VI](yield: 94 %, bp: 70° C./1 mmHg).

출처 및 근거

ORD 기록
ord-3376072a56c14acaa0243404943cc2f8
출처 데이터셋
uspto-grants-1989_06
특허 번호
US04837339

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