2,5-Furandimethanol → 2,5-Tetrahydrofurandimethanol

HRID 1921603

반응식

HRID 1921603 반응식
[OH:1][CH2:2][C:3]1[O:7][C:6]([CH2:8][OH:9])=[CH:5][CH:4]=1.[H][H]>[Ni].C(O)C>[OH:9][CH2:8][CH:6]1[O:7][CH:3]([CH2:2][OH:1])[CH2:4][CH2:5]1

참가 물질

5

반응물 2

HCID 746632,5-FurandimethanolHCID 178418361HCID 178418361, 화합물

생성물 1

HCID 977922,5-Tetrahydrofurandimethanol

시약·촉매·용매 2

HCID 935Nickel촉매HCID 702Ethanol용매

실험 절차

Raney nickel [ethanol was added three times to 50% commercial aqueous Raney nickel suspension (5 mL) from Acros, and decanted] was added to a solution of (5-hydroxymethylfuran-2-yl)methanol (RK-325) (3.46 g, 27 mmol) in absolute ethanol (100 mL), and hydrogenated overnight at room temperature and at a pressure of 2 bar (hydrogen consumption 61 mmol). The reaction mixture was filtered and the filtrate was concentrated under vacuum.

후처리

  1. filtrationThe reaction mixture was filtered
  2. concentrationthe filtrate was concentrated under vacuum

출처 및 근거

ORD 기록
ord-7cb275e0c6744cc492427a38fcf243d7
출처 데이터셋
uspto-grants-2012_05
특허 번호
US08173700B2

연결된 노트

불러오는 중…