(+-)-2-Butanol → 2-((R)-sec-Butoxy)-5-methanesulfonyl-benzoic acid

HRID 1931007노트

반응식

HRID 1931007 반응식
F[C:2]1[CH:10]=[CH:9][C:8]([S:11]([CH3:14])(=[O:13])=[O:12])=[CH:7][C:3]=1[C:4]([OH:6])=[O:5].[CH3:15][CH2:16][CH:17]([OH:19])[CH3:18]>>[C@H:17]([O:19][C:2]1[CH:10]=[CH:9][C:8]([S:11]([CH3:14])(=[O:13])=[O:12])=[CH:7][C:3]=1[C:4]([OH:6])=[O:5])([CH2:16][CH3:15])[CH3:18]

참가 물질

3

반응물 2

HCID 6568(+-)-2-ButanolHCID 224675662-Fluoro-5-methanesulfonyl-benzoic acid

생성물 1

HCID 588633572-((R)-sec-Butoxy)-5-methanesulfonyl-benzoic acid

실험 절차

Prepared in analogy to Example B4(c) from 2-Fluoro-5-methanesulfonyl-benzoic acid (example B4(b)) and R-(−)-2-butanol. White solid. MS (m/e): 271.1 ([M−H], 100%).

출처 및 근거

ORD 기록
ord-d0473b34260544a99303f7e9f2440add
출처 데이터셋
uspto-grants-2012_05
특허 번호
US08188139B2

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