Dichloromethane → Acetic Acid 4,5-bis-Benzyloxy-6-benzyloxymethyl-2-hydroxy-tetrahydropyran-3-yl Ester

HRID 193514

반응식

HRID 193514 반응식
[CH3:43][Si:44]([O:45][S:46]([C:47]([F:48])([F:49])[F:50])(=[O:51])=[O:52])([CH3:53])[CH3:54].[Cl:1][C:2]([Cl:3])([Cl:40])[C:41]([O:4][CH:5]1[CH:6]([O:7][C:8]([CH3:9])=[O:10])[CH:11]([O:12][CH2:13][c:14]2[cH:15][cH:16][cH:17][cH:18][cH:19]2)[CH:20]([O:21][CH2:22][c:23]2[cH:24][cH:25][cH:26][cH:27][cH:28]2)[CH:29]([CH2:31][O:32][CH2:33][c:34]2[cH:35][cH:36][cH:37][cH:38][cH:39]2)[O:30]1)=[NH:42].[Cl:55][CH2:56][Cl:57]>>[OH:4][CH:5]1[CH:6]([O:7][C:8]([CH3:9])=[O:10])[CH:11]([O:12][CH2:13][c:14]2[cH:15][cH:16][cH:17][cH:18][cH:19]2)[CH:20]([O:21][CH2:22][c:23]2[cH:24][cH:25][cH:26][cH:27][cH:28]2)[CH:29]([CH2:31][O:32][CH2:33][c:34]2[cH:35][cH:36][cH:37][cH:38][cH:39]2)[O:30]1

참가 물질

4

반응물 3

HCID 6344DichloromethaneHCID 65367Trimethylsilyl triflateHCID 138730772-o-Acetyl-3,4,6-tri-o-benzyl-a-d-mannopyranosyl trichloroacetimidate

생성물 1

HCID 13873073Acetic Acid 4,5-bis-Benzyloxy-6-benzyloxymethyl-2-hydroxy-tetrahydropyran-3-yl Ester

출처 및 근거

ORD 기록
ord-1e3de13562ae4b6aa7ec1b7424227ee0
출처 데이터셋
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

연결된 노트

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