Trichlorosilane → 1,1,1,3,3-Pentachloro-1,3-disilabutane
반응식
Cl[CH2:2][Si:3]([CH3:6])([Cl:5])[Cl:4].[Cl:7][SiH:8]([Cl:10])[Cl:9]>[Cl-].C([P+](CCCC)(CCCC)CCCC)CCC>[Cl:7][Si:8]([Cl:10])([Cl:9])[CH2:2][Si:3]([Cl:5])([Cl:4])[CH3:6]참가 물질
4
실험 절차
In the same apparatus and procedure as Example 1 above, 0.18 g (0.61 mmol) of tetrabutylphosphonium chloride, 1.00 g (6.12 mmol) of (chloromethyl)methyldichlorosilane, and 2.52 g (18.6 mmol) of trichlorosilane were reacted at 150° C. for 2 hrs. The resulting mixture was distilled to give 0.96 g of 1,1,1,3,3-pentachloro-1,3-disilabutane (yield; 60%).
후처리
- distillationThe resulting mixture was distilled
출처 및 근거
- ORD 기록
- ord-e6350986c53a4590ab8853aecf7aa8f4
- 출처 데이터셋
- uspto-grants-2002_05
- 특허 번호
- US06392077B1
반응 노트
불러오는 중…