Dimethyl Sulfoxide → 1,1'-Disulfanediylbis(2-chlorobenzene)

HRID 1963688

반응식

HRID 1963688 반응식
C[Si](C)(C)N[Si](C)(C)C.[Cl:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=1[SH:17].C[S:19]([CH3:21])=O>C(#N)C>[Cl:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=1[S:17][S:19][C:21]1[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=1[Cl:10]

참가 물질

5

반응물 3

HCID 679Dimethyl SulfoxideHCID 13838HexamethyldisilazaneHCID 80599o-Chlorothiophenol

생성물 1

HCID 2334821,1'-Disulfanediylbis(2-chlorobenzene)

시약·촉매·용매 1

HCID 6342Acetonitrile용매

실험 절차

Hexamethyldisilazane (4.4 ml) was added to a stirred solution of 2-chlorobenzenethiol (2.0 ml) and DMSO (3.7 ml) in dry acetonitrile at room temperature. After 2 h the white precipitate was filtered and washed (cold acetonitrile) to give the sub-title compound as a white solid (2.27 g).

후처리

  1. filtrationAfter 2 h the white precipitate was filtered
  2. washwashed (cold acetonitrile)

출처 및 근거

ORD 기록
ord-e8d37b29b0a04cc6a9a7475fed1a8408
출처 데이터셋
uspto-grants-2013_04
특허 번호
US08415394B2

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