2-Chlorocyclohexanone → 2,3-Dimethyl-2,3,5,6,7,8-hexahydro-1,4-benzodithiine

HRID 1973331

반응식

HRID 1973331 반응식
[CH3:1][CH:2]([SH:6])[CH:3]([SH:5])[CH3:4].Cl[CH:8]1[CH2:13][CH2:12][CH2:11][CH2:10][C:9]1=O>>[CH3:1][CH:2]1[S:6][C:9]2[CH2:10][CH2:11][CH2:12][CH2:13][C:8]=2[S:5][CH:3]1[CH3:4]

참가 물질

3

반응물 2

HCID 132032-ChlorocyclohexanoneHCID 5483532,3-Butanedithiol

생성물 1

HCID 129200542,3-Dimethyl-2,3,5,6,7,8-hexahydro-1,4-benzodithiine수율 49%

실험 절차

The procedure of Example 1(a) is followed using 2,3-butanedithiol and 2-chlorocyclohexanone to give 5,6,7,8-tetrahydro-2,3-dimethyl-1,4-benzodithian as a greenish oil, b.p. 90°-100°/0.07 mm. Yield 49%. NMR 1.34 (6d), 1.45-2.25 (8m), 2.7-3.1 (2m). IR 2900, 1610, 1435, 1365, 1320, 1115, 795, 690.

출처 및 근거

ORD 기록
ord-8056b03b1f3c4fac88325a493db41bbe
출처 데이터셋
uspto-grants-1976_12
특허 번호
US03997323

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