Sodium Hydroxide → 1-Aminoanthraquinone

HRID 1973440

반응식

HRID 1973440 반응식
[NH:1]([C:5]1[C:18]2[C:17](=[O:19])[C:16]3[C:11](=[CH:12][CH:13]=[CH:14][CH:15]=3)[C:10](=[O:20])[C:9]=2[CH:8]=[CH:7][CH:6]=1)C(C)=O.[OH-].[Na+]>O>[NH2:1][C:5]1[C:18]2[C:17](=[O:19])[C:16]3[C:11](=[CH:12][CH:13]=[CH:14][CH:15]=3)[C:10](=[O:20])[C:9]=2[CH:8]=[CH:7][CH:6]=1

참가 물질

4

반응물 2

HCID 14798Sodium HydroxideHCID 76760N-Anthraquinon-1-ylacetamide

생성물 1

HCID 67101-Aminoanthraquinone수율 98.1%

시약·촉매·용매 1

HCID 962Water용매

실험 절차

363 g (1.37 moles) of 1-acetamino-anthraquinone are warmed with 3.5 l of water and 130 ml of concentrated sodium hydroxide solution (d = 1.48) in a stainless steel autoclave for 5 hours at 150° C. After cooling to room temperature, the red suspension is filtered. The residue is washed with hot water until neutral. After drying, 300 g of 1-amino-anthraquinone are obtained (yield: 98%). Degree of purity: 97 to 98%.

후처리

  1. filtrationthe red suspension is filtered
  2. washThe residue is washed with hot water until neutral
  3. customAfter drying

출처 및 근거

ORD 기록
ord-15b88242441b4cc6a49b22556bbd0f6b
출처 데이터셋
uspto-grants-1976_12
특허 번호
US03997573

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