Idramantone → 1-Acryloyloxyadamantane-4-one

HRID 1978124

반응식

[C:1](OCC12CC3CC(CC(O)(C3)C1)C2)(=[O:4])[CH:2]=[CH2:3].[OH:18][C:19]12[CH2:28][CH:23]3[CH2:24][CH:25]([CH2:27][CH:21]([C:22]3=[O:29])[CH2:20]1)[CH2:26]2>>[C:1]([O:18][C:19]12[CH2:28][CH:23]3[CH2:24][CH:25]([CH2:27][CH:21]([C:22]3=[O:29])[CH2:20]1)[CH2:26]2)(=[O:4])[CH:2]=[CH2:3]

참가 물질

반응물 2

HCID 64184Idramantone

HCID 219967831-Hydroxy-3-(acryloyloxymethyl)adamantane

생성물 1

HCID 219306931-Acryloyloxyadamantane-4-one수율 95%

실험 절차

The reaction was conducted in the same manner as said (2) except that 1-hydroxyadamantane-4-one was used instead of the 1-hydroxyadamantane-2-one, and, as a result, a 1-acryloyloxyadamantane-4-one (yield: 95%, white solid) was obtained.

출처 및 근거

ORD 기록: ord-36ce7df095ef484f961f53dc3227ed81
출처 데이터셋: uspto-grants-2001_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06235851B1

연결된 노트

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