Phosphorus pentachloride → 2-Benzyl-3-chloro-5-methoxy-2H-1,2,4,6-thiatriazine-1,1-dioxide
반응식
[CH2:1]([N:8]1[C:13](=O)[NH:12][C:11]([O:15][CH3:16])=[N:10][S:9]1(=[O:18])=[O:17])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.P(Cl)(Cl)(Cl)(Cl)[Cl:20]>O=P(Cl)(Cl)Cl>[CH2:1]([N:8]1[C:13]([Cl:20])=[N:12][C:11]([O:15][CH3:16])=[N:10][S:9]1(=[O:18])=[O:17])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1참가 물질
4
실험 절차
A stirred mixture of 2-benzyl-5-methoxy-2H-1,2,4,6-thiatriazin-3-one-1,1-dioxide (10.5 g) and PCl5 (12.2 g) in POCl3 (35 ml) is refluxed overnight. The reaction mixture is evaporated in vacuo at 50° C. affording the crude product as an oil.
후처리
- temperatureis refluxed overnight
- customThe reaction mixture is evaporated in vacuo at 50° C.
출처 및 근거
- ORD 기록
- ord-a26e4fd0992c45289367e3b8e590e514
- 출처 데이터셋
- uspto-grants-1986_06
- 특허 번호
- US04595683
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