Ethyl tert-butyl ether → Hydrogen Peroxide

HRID 1985584

반응식

HRID 1985584 반응식
[O:1]=[O+:2][O-].[C:4]([O:8][CH2:9]C)([CH3:7])([CH3:6])[CH3:5].[O:11]=[O+][O-].OO>C(OC)(C)(C)C>[CH:9]([O:8][C:4]([CH3:7])([CH3:6])[CH3:5])=[O:11].[OH:1][OH:2]

참가 물질

6

반응물 3

HCID 12512Ethyl tert-butyl etherHCID 24823Ozone4회HCID 86602708Ozone Hydrogen Peroxide

생성물 2

HCID 784Hydrogen PeroxideHCID 61207tert-Butyl Formate

시약·촉매·용매 1

HCID 15413tert-Butyl methyl ether용매4회

실험 절차

Referring to FIG. 12, primary and secondary reactions of MTBE with Ozone are shown. Karpel vel Leitner, R. N., A. L Papailhous, J. P. Crove, J. Payrot, and M. Dore (1994) “Oxidation of Methyl tert-Butyl Ether (MTBE) and Ethyl tert-Butyl Ether (ETBE) by Ozone and Combined Ozone/Hydrogen Peroxide” Ozone Science and Engineering 16, 41-54, described reaction pathways of ozone and MTBE in dilute aqueous solution using controlled experimental conditions. The primary reaction (90% of the consumed mass of MTBE) results in the formation of tert-butyl formate and hydrogen peroxide. A second parallel reaction (less than 10% of the consumed mass of MTBE) generates formaldehyde, TBA, and oxygen.

출처 및 근거

ORD 기록
ord-30a8bffd86224d9a87fcbdb6db2904f4
출처 데이터셋
uspto-grants-2009_06
특허 번호
US07547388B2

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