Hydrochloric Acid → Myristyl chloride

HRID 1994377노트

반응식

HRID 1994377 반응식
[CH2:1](O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].[ClH:16]>O>[CH2:1]([Cl:16])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14]

참가 물질

4

반응물 2

HCID 313Hydrochloric AcidHCID 82091-Tetradecanol

생성물 1

HCID 17043Myristyl chloride

시약·촉매·용매 1

HCID 962Water용매2회

실험 절차

A 1 l jacketed glass reactor with a glass paddle stirrer, an immersed tube for reactant metering and an attached water separator is initially charged with 200 g of N-n-octylalkylpyridinium chloride (prepared according to Example 2) as catalyst and adjusted to a temperature of 150° C. 243 g of n-tetradecanol are introduced uniformly via the immersed tube within 4.5 h. Over the entire reaction time, gaseous hydrogen chloride in a slight excess is metered in via the immersed tube, while the water of reaction formed is removed distillatively from the reaction mixture. The performance of the reaction and workup are analogous to Example 4a. After a total reaction time of 7.5 h, the conversion based on n-tetradecanol is 99.5%.

후처리

  1. customadjusted to a temperature of 150° C
  2. customformed
  3. customis removed distillatively from the reaction mixture
  4. customThe performance of the reaction and workup
  5. customAfter a total reaction time of 7.5 h

출처 및 근거

ORD 기록
ord-ba5422b6b1d14df6b23f24a769c8cdb4
출처 데이터셋
uspto-grants-2010_01
특허 번호
US07652180B2

반응 노트

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