Pyridine → N-(chloroacetoxy)-3-chloro-N-(2-chlorophenyl)methyl-2,2-dimethylpropanamide

HRID 1995483

반응식

HRID 1995483 반응식
[Cl:1][CH2:2][C:3]([CH3:17])([CH3:16])[C:4]([N:6]([CH2:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=1[Cl:15])[OH:7])=[O:5].[Cl:18][CH2:19][C:20](Cl)=[O:21].N1C=CC=CC=1>C1(C)C=CC=CC=1>[Cl:18][CH2:19][C:20]([O:7][N:6]([CH2:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=1[Cl:15])[C:4](=[O:5])[C:3]([CH3:17])([CH3:16])[CH2:2][Cl:1])=[O:21]

참가 물질

5

반응물 3

HCID 1049PyridineHCID 6577Chloroacetyl chlorideHCID 99255583-chloro-N-(2-chlorophenyl)methyl-N-hydroxy-2,2-dimethylpropanamide

생성물 1

HCID 13192525N-(chloroacetoxy)-3-chloro-N-(2-chlorophenyl)methyl-2,2-dimethylpropanamide

시약·촉매·용매 1

HCID 1140Toluene용매

실험 절차

This compound was prepared in the manner of Example 13, using 4.0 g (0.014 mole) of 3-chloro-N-(2-chlorophenyl)methyl-N-hydroxy-2,2-dimethylpropanamide (prepared in Example 1), 1.6 g (0.014 mole) of chloroacetyl chloride, and 1.2 g (0.015 mole) of pyridine, in 50 ml toluene. The product was a liquid, of which nmr and ir spectra were consistent with the assigned structure.

후처리

  1. customThis compound was prepared in the manner of Example 13

출처 및 근거

ORD 기록
ord-9ad350d0eae44ae09e8fa8044bb1c917
출처 데이터셋
uspto-grants-1983_09
특허 번호
US04405357

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