Nitric Acid → HCID 20342728, 화합물

HRID 2049898노트

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HRID 2049898 반응식
CCOCC.[C:6]1([CH3:16])[CH:11]=[CH:10][CH:9]=[CH:8][C:7]=1[O:12][CH:13]([CH3:15])[CH3:14].C(OC(=O)C)(=O)C.[N+:24]([O-])([OH:26])=[O:25]>C(O)(=O)C.O>[CH:13]([O:12][C:7]1[CH:8]=[CH:9][C:10]([N+:24]([O-:26])=[O:25])=[CH:11][C:6]=1[CH3:16])([CH3:14])[CH3:15]

참가 물질

7

반응물 4

HCID 944Nitric AcidHCID 3283Diethyl EtherHCID 7918Acetic AnhydrideHCID 141785Benzene, 1-methyl-2-(1-methylethoxy)-

생성물 1

HCID 20342728HCID 20342728, 화합물

시약·촉매·용매 2

HCID 176Acetic Acid용매2회HCID 962Water용매

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온도
6 °C

실험 절차

To a chilled (6° C.) solution contaning 31.8 g (0.2 mol) of the ether prepared as in (a) above and 28.7 g of acetic anhydride in 200 ml of glacial acetic acid was added dropwise a solution of 13.9 g (0.22 mol) of 90% nitric acid in 100 ml of glacial acetic acid. The reaction mixture was allowed to stand at ambient temperature for 12 hours, poured into water and extracted with methylene chloride. The extract was washed with 5% sodium carbonate, water, dried, and concentrated to give 21.8 g of product as an amber oil.

후처리

  1. extractionextracted with methylene chloride
  2. washThe extract was washed with 5% sodium carbonate, water
  3. customdried
  4. concentrationconcentrated

출처 및 근거

ORD 기록
ord-841dcbfdc1dd48bb82b15ea78b8659d0
출처 데이터셋
uspto-grants-1980_04
특허 번호
US04199347

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