반응식
[Cl:1][C:2]([F:8])(I)[C:3]([F:6])([F:5])[Cl:4].[CH2:9]([Si](C)(C)C)[CH:10]=[CH2:11].N(C(C)(C)C#N)=NC(C)(C)C#N>>[Cl:1][C:2]([F:8])([C:3]([Cl:4])([F:6])[F:5])[CH2:11][CH:10]=[CH2:9]참가 물질
4
반응 조건
- 온도
- 80 °C
실험 절차
A mixture of 279 mg (1.0 mmol) of 1,2-dichloro-1-iodotrifluoroethane, 114 mg (1.0 mmol) of allyltrimethylsilane and 10 mg (0.06 mmol) of azobisisobutyronitrile (AIBN) was heated in a sealed glass tube at 80° C. for 3 hours. After cooling, 10 mg (0.06 mmol) of AIBN was added to the mixture, followed by heating in a sealed tube at 80° C. for 3 hours to obtain 4,5-dichloro-4,5,5-trifluoro-1-pentene (Compound 39) in a yield of 40%.
후처리
- temperatureAfter cooling
- temperatureby heating in a sealed tube at 80° C. for 3 hours
출처 및 근거
- ORD 기록
- ord-d8addac6ff36493095b54b0b6f44107e
- 출처 데이터셋
- uspto-grants-1991_05
- 특허 번호
- US05017718
연결된 노트
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