Safrole → Safrole oxide

HRID 2057692

반응식

HRID 2057692 반응식
[CH2:1]([C:4]1[CH:12]=[CH:11][C:7]2[O:8][CH2:9][O:10][C:6]=2[CH:5]=1)[CH:2]=[CH2:3].CCC(OO)=[O:16]>CCC(Cl)Cl>[O:16]1[CH2:3][CH:2]1[CH2:1][C:4]1[CH:12]=[CH:11][C:7]2[O:8][CH2:9][O:10][C:6]=2[CH:5]=1

참가 물질

4

반응물 2

HCID 5144SafroleHCID 65136Perpropionic acid

생성물 1

HCID 101123Safrole oxide

시약·촉매·용매 1

HCID 65731,1-Dichloropropane용매

실험 절차

48.82 g (0.3 mol) of 5-(2-propenyl)-1,3-benzodioxole were reacted with 45 g (0.1 mol) of a 20% strength solution of perpropionic acid in dichloropropane at 30° C. as described in Example 1. After a reaction time of 6 hours, the peracid conversion was 96%. 5-(Oxiranylmethyl)-1,3-benzodioxole was formed with a selectivity of 68%.

후처리

  1. customAfter a reaction time of 6 hours

출처 및 근거

ORD 기록
ord-0e6bb625f7d6498f99187530cf82f287
출처 데이터셋
uspto-grants-1980_07
특허 번호
US04212809

연결된 노트

불러오는 중…